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This study investigates the programmable strain sensing capability, auxetic behaviour, and failure modes of 3D-printed, self-monitoring auxetic lattices fabricated from in-house engineered polyetheretherketone (PEEK) reinforced with multi-walled carbon nanotubes (MWCNTs). A skeletally-parametrized geometric modelling framework, combining Voronoi tessellation with 2D wallpaper symmetries, is used to systematically explore a vast range of non-predetermined topologies beyond traditional lattice designs. A representative set of these architectures is realized via fused filament fabrication, and multiscale characterization—including macroscale tensile testing and microstructural analysis—demonstrates tuneable multifunctional performance as a function of MWCNT content and unit cell topology. Real-time resistance measurements track deformation, damage initiation, and progression, with the sensitivity factor increasing from below 1 in the elastic regime (strain sensitivity) to as high as 80 for PEEK/MWCNT at 6 wt.% under inelastic deformation (damage sensitivity). Implicit architecture-topology tailoring further allows fine-tuning of mechanical properties, achieving stiffness values ranging from 9 MPa to 63 MPa and negative Poisson’s ratios between –0.63 and –0.17 using ~3 wt.% MWCNT at a relative density of 25%. Furthermore, a novel piezoresistive finite element model, implemented in Abaqus via a user-defined subroutine, accurately captures the electromechanical response up to the onset of ligament failure, offering predictive capability. These results demonstrate how architecture-topology tuning can be leveraged to customise strain sensitivity and failure modes, enabling the development of multifunctional piezoresistive lattice composites for applications such as smart orthopaedic implants, aerospace skins, and impact-tolerant systems. 

Abstract. Secondary organic aerosol (SOA) is a dominant contributor of fine particulate matter in the atmosphere, but the complexity of SOA formation chemistry hinders the accurate representation of SOA in models. Volatility-based SOA parameterizations have been adopted in many recent chemistry modeling studies and have shown a reasonable performance compared to observations. However, assumptions made in these empirical parameterizations can lead to substantial errors when applied to future climatic conditions as they do not include the mechanistic understanding of processes but are rather fitted to laboratory studies of SOA formation. This is particularly the case for SOA derived from isoprene epoxydiols (IEPOX SOA), for which we have a higher level of understanding of the fundamental processes than is currently parameterized in most models. We predict future SOA concentrations using an explicit mechanism and compare the predictions with the empirical parameterization based on the volatility basis set (VBS) approach. We then use the Community Earth System Model 2 (CESM2.1.0) with detailed isoprene chemistry and reactive uptake processes for the middle and end of the 21st century under four Shared Socioeconomic Pathways (SSPs): SSP1–2.6, SSP2–4.5, SSP3–7.0, and SSP5–8.5. With the explicit chemical mechanism, we find that IEPOX SOA is predicted to increase on average under all future SSP scenarios but with some variability in the results depending on regions and the scenario chosen. Isoprene emissions are the main driver of IEPOX SOA changes in the future climate, but the IEPOX SOA yield from isoprene emissions also changes by up to 50 % depending on the SSP scenario, in particular due to different sulfur emissions. We conduct sensitivity simulations with and without CO2 inhibition of isoprene emissions that is highly uncertain, which results in factor of 2 differences in the predicted IEPOX SOA global burden, especially for the high-CO2 scenarios (SSP3–7.0 and SSP5–8.5). Aerosol pH also plays a critical role in the IEPOX SOA formation rate, requiring accurate calculation of aerosol pH in chemistry models. On the other hand, isoprene SOA calculated with the VBS scheme predicts a nearly constant SOA yield from isoprene emissions across all SSP scenarios; as a result, it mostly follows isoprene emissions regardless of region and scenario. This is because the VBS scheme does not consider heterogeneous chemistry; in other words, there is no dependency on aerosol properties. The discrepancy between the explicit mechanism and VBS parameterization in this study is likely to occur for other SOA components as well, which may also have dependencies that cannot be captured by VBS parameterizations. This study highlights the need for more explicit chemistry or for parameterizations that capture the dependence on key physicochemical drivers when predicting SOA concentrations for climate studies.